12-Ring Network Coordination Polymer——{[Cu(C_4N_2H_(10))_4]_2·H_4V_4O_(14)}_n Formed by Linking cyclo-[H_4V_4O_(14)]~(4-) with Cu(C_4N_2H_(10))~(2+)_4 Cation Clusters

IntroductionThe interest in polyoxometalates that are widelyused in medical chemistry, catalyst reactions, and ma-terial sciences stems from their complicated aggregatesformed by means of corner-, edge- and face-sha-ring[1—4]. The exploitation of new str…     

Monitoring the Aggregation of Dansyl Chloride in Acetone through Fluorescence Measurements

The aggregation of dansyl chloride (DNS-Cl) in acetone has been studied in detail by steady-state fluorescence techniques.It has been demonstrated that DNS-Cl is stable in acetone during purification and aggregation study processes.The aggregates are not solvolyzed in acetone,and do not take part n any chemical reactions either.It has been found that DNS-Cl tends to aggregate even when its concentration is much lower than its solubility in acetone.The aggregation is reversible,and both the aggregation and the deaggregation are very slow processes.Introduction of SDS has a positive effect upon the formation and stabilization of the aggregates.     

基于变芯径光纤的光学系统在光造型中的应用

光学系统采用变芯径光纤，可大幅度提高光的传输效率，增加光学子系统柔性。描述了光造型工作原理及其理论依据，在介绍所研制的光的成型系统光学子系统的基础上，阐述了紫外光源的选择与设计，及变芯径光纤的设计、传输、耦合与聚焦等技术。该套基于变芯径光纤的光学子系统成本低、体积小、效率高，巳成功应用于所研制的台式低成本快速成型系统中，为该系统的进一步推广奠定了技术基础。     

HIGH ACCURACY FINITE VOLUME ELEMENT METHOD FOR TWO-POINT BOUNDARY VALUE PROBLEM OF SECOND ORDER ORDINARY DIFFERENTIAL EQUATIONS

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MAURER-CARTAN EQUATION OF A_∞-ALGEBRAS

§ 0　IntroductionA∞ - algebras were first introduced and applied by Stasheff in [12 ,13].Recently,theyappeared in both mathematics and mathematical physics[1 ,5— 8,1 0 ] .An A∞ - algebra is a Z-graded vector space over a fixed field k with a sequence of graded maps mn∶ A n→ A ofdegree n- 2 (n≥ 1) satisfying certain axioms (see [5 ,6 ,12 ,13]) .In this paper,we focusour attentions on,as we call,the minimal A∞ - algebras,which are usual A∞ - algebrasdefined in [5 ,6 ,12 ,13]with m1 =…     

INVERSE EIGENVALUE PROBLEM OF HERMITIAN GENERALIZED ANTI-HAMILTONIAN MATRICES

§1　IntroductionWe considerthe following inverse eigenvalue problem offinding an n-by-n matrix A∈S such thatAxi =λixi,i =1,2 ,...,m,where S is a given set of n-by-n matrices,x1 ,...,xm(m≤n) are given n-vectors andλ1 ,...,λmare given constants.Let X=(x1 ,...,xm) ,Λ=(λ1 ,λ2 ,...,λm) ,then the above inverse eigenvalue problemcan be written as followsProblem Given X∈Cn×m,Λ=(λ1 ,...,λm) ,find A∈S such thatAX =XΛ,where S is a given matrix set.We also discuss the so-called opti…     

带有不等式约束的全局最优性条件

本文利用不连续罚函数方法将带有不等式约束的全局优化问题的求解转化为 讨论一非线性方程的求根问题,从而得到若干个全局最优性条件.     

Bio-regeneration of p-complexation desulfurization adsorbents

More and more stringent regulations of gasoline and diesel oil were proposed with the awareness of environmental protection. Hydrodesulfurization (HDS) is a conventional method to remove sulfur compounds for industrial purpose. The main drawbacks of this …     

有机化合物电子光谱中的助色基及其作用机理探讨(Ⅰ)

本文就电子光谱中助色基的作用进行了讨论 ,认为不能一概地认为助色基能使与之相连的生色基最大吸收波长统统发生红移 ,而应具体问题具体分析 :对于n→π 来说 ,一方面助色基的p轨道和生色基的最低π 反键空轨道相互作用 ,使π 反键轨道能量上升 ,另一方面助色基的p轨道和生色基的n轨道正交 ,n轨道能量基本保持不变 ,因此n→π 跃迁能增加 ,吸收波长发生蓝移。对于π→π 跃迁来说 ,助色基的p轨道和生色基的最高π成键轨道相互作用生成的新的最高π成键轨道 ,能量虽然有所升高 ,但升高的程度与π 反键轨道升高的程度相比 ,在一些化合物中π轨道升高程度较大 ,因而π→π 跃迁能减小 ,吸收波长发生红移 ;在另一些化合物中π轨道升高程度较小 ,因而π→π 跃迁能增加 ,吸收波长发生蓝移。     

非本征型法布里-珀罗干涉仪光纤布拉格光栅应变温度传感器及其应用

介绍了光纤布拉格光栅非本征型法布里珀罗干涉仪集成复用传感器的结构、应变和温度同时监测的原理 ;观察到光纤布拉格光栅反射谱和非本征型法布里珀罗干涉仪干涉谱间的串扰 ,用 3dB带宽平均波长法减小了该串扰 ,提高了测量精度 ;将该传感器应用于三维编织复合材料的应变及温度同时监测。实验结果表明温度精度为± 1℃ ,应变精度为± 2 0 μ ,可满足实际应用的要求